New process converts old PLA plastic into a better 3D-printing resin
06/09/2022
Bioplastics
Although plant-based polylactic acid (PLA) bioplastic is acclaimed for its biodegradability, it can take quite a long time to degrade if the conditions aren't quite right. Bearing this fact in mind, Washington State University scientists have devised a way of upcycling it into a 3D-printing resin.
"[PLA] is biodegradable and compostable, but once you look into it, it turns out that it can take up to 100 years for it to decompose in a landfill," said postdoctoral researcher Yu-Chung Chang, co-corresponding author of the study. "In reality, it still creates a lot of pollution. We want to make sure that when we do start producing PLA on the million-tons scale, we will know how to deal with it."
To that end, Chang and colleagues developed a process in which an inexpensive chemical known as aminoethanol is used to break down the long chains of molecules that make up PLA. Those chains are rendered into simple monomers, which are the basic building blocks of plastic. The process takes about two days, and can be carried out at mild temperatures.
Next, the monomers are recombined to form a light-curable resin, similar to those already utilized in some 3D printers. In fact, when used in the 3D-printing of test objects, the PLA-derived resin was found to exhibit mechanical and thermal qualities which were equal to or better than those of existing commercial resins.
We found a way to immediately turn this into something that’s stronger and better, and we hope that will provide people the incentive to upcycle this stuff instead of just toss it away," said Chang. "We made stronger materials just straight out of trash. We believe this could be a great opportunity." The scientists are now hoping to apply the technique to another type of commonly used plastic, called polyethylene terephthalate (PET). A paper on the research, which is being led by Prof. Jinwen Zhang, was recently published in the journal Green Chemistry.
New process converts old PLA plastic into a better 3D-printing resin
06/09/2022
Bioplastics
Although plant-based polylactic acid (PLA) bioplastic is acclaimed for its biodegradability, it can take quite a long time to degrade if the conditions aren't quite right. Bearing this fact in mind, Washington State University scientists have devised a way of upcycling it into a 3D-printing resin.
"[PLA] is biodegradable and compostable, but once you look into it, it turns out that it can take up to 100 years for it to decompose in a landfill," said postdoctoral researcher Yu-Chung Chang, co-corresponding author of the study. "In reality, it still creates a lot of pollution. We want to make sure that when we do start producing PLA on the million-tons scale, we will know how to deal with it."
To that end, Chang and colleagues developed a process in which an inexpensive chemical known as aminoethanol is used to break down the long chains of molecules that make up PLA. Those chains are rendered into simple monomers, which are the basic building blocks of plastic. The process takes about two days, and can be carried out at mild temperatures.
Next, the monomers are recombined to form a light-curable resin, similar to those already utilized in some 3D printers. In fact, when used in the 3D-printing of test objects, the PLA-derived resin was found to exhibit mechanical and thermal qualities which were equal to or better than those of existing commercial resins.
We found a way to immediately turn this into something that’s stronger and better, and we hope that will provide people the incentive to upcycle this stuff instead of just toss it away," said Chang. "We made stronger materials just straight out of trash. We believe this could be a great opportunity." The scientists are now hoping to apply the technique to another type of commonly used plastic, called polyethylene terephthalate (PET). A paper on the research, which is being led by Prof. Jinwen Zhang, was recently published in the journal Green Chemistry.
